The show, One Night Only, will be shown on ITV later this month and it will be filmed in front of an audience in London.
The band will perform some of their biggest hits such as Girls on Film and Rio before its members - Simon Le Bon, Nick Rhodes, John Taylor and Roger Taylor - will be seen giving interviews in footage shown to the audience.
UK TV host Christine Bleakley, star of ITV1 breakfast show Daybreak, will be hosting the show.
Speaking about the programme, band member Le Bon said: 'We are very excited to be a part of the One Night Only series as we really like the format.
'We always enjoy performing in front of a live audience and this will be the first opportunity for us to play some songs from our new album, All You Need Is Now.'