The rocker, whose famous songs include Do Ya Think I'm Sexy, Maggie May and Sailing will entertain family and friends at his estate in Gloucestershire.
The party comes two days before the release of Rod's new Greatest Hits release; 'Some Guys Have All The Luck' – a collection of his work on the Warner Music label, which will be available as a two disc CD and three disc deluxe edition with an exclusive DVD of music videos and is release on the 17th of November on Rhino.
Stewart, an ambassador for the Prince's charity the Prince's Trust, will provide the main musical entertainment at the party being hosted by the Duchess of Cornwall on November 15.
The Prince turns 60 on November 14 and will celebrate the occasion with a prior event the day before his birthday at Buckingham Palace, where the Queen will host a private reception for the Prince and other senior royals, including Camilla, and a concert, at which The Philharmonia Orchestra, which has the Prince as its patron, will provide the music.